Benzaldehyde thiosemicarbazone monohydrate
نویسندگان
چکیده
In the title compound, C(8)H(9)N(3)S·H(2)O, intra-molecular N-H⋯N hydrogen bonding contributes to the mol-ecular conformation. Water mol-ecules are involved in inter-molecular N-H⋯O and O-H⋯S hydrogen bonds, which link the mol-ecules into ribbons extended along the a axis. Weak inter-molecular N-H⋯S hydrogen bonds link these ribbons into layers parallel to the ab plane with the phenyl rings pointing up and down.
منابع مشابه
(E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone
In the title compound, C(15)H(15)N(3)OS, the thio-semicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thio-semicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benz-yloxy and phenyl rings is 72.48 (5)°. In the crystal structure, mol-ecules are inter-connected by N-H⋯N and N-H⋯S hydrogen bonds, fo...
متن کاملBenzaldehyde thiosemicarbazone
The title compound, C(8)H(9)N(3)S, contains two mol-ecules in the asymmetric unit. One mol-ecule is close to being planar (r.m.s. deviation from the mean plane = 0.06 Å for the non-H atoms), while the other exhibits a dihedral angle of 21.7 (1)° between the benzene ring and the mean plane of the thio-semicarbazone unit. Inter-molecular N-H⋯S hydrogen bonds link the mol-ecules into layers parall...
متن کامل2-Hydroxy-4-methoxybenzaldehyde thiosemicarbazone
The title Schiff base compound, C(9)H(11)N(3)O(2)S, was prepared by the reaction of equimolar quanti-ties of 2-hy-droxy-4-meth-oxy-benzaldehyde with thio-semicarbazide in methanol. The mol-ecule adopts a trans configuration with respect to the azo-methine group and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring. In the crystal structure, mol-ecules are linked through inter-molecu...
متن کامل2-Chloro-5-nitrobenzaldehyde thiosemicarbazone
The title Schiff base compound, C(8)H(7)ClN(4)O(2)S, was prepared by the reaction of equimolar quanti-ties of 2-chloro-5-nitro-benzaldehyde with thio-semicarbazide in methanol. The mol-ecule adopts a trans configuration with respect to the azomethine group and the dihedral angle between the benzene ring and the thio-semicarbazide group is 6.8 (3)°. In the crystal, mol-ecules are linked through ...
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The title compound, C(10)H(8)N(4)O(4)·H(2)O, was obtained by the reaction of 5-hy-droxy-2-nitro-benzaldehyde with cyano-acetohydrazide in methanol. The non-H atoms of the hydrazone molecule are approximately coplanar, with a mean deviation from the least-squares plane of 0.056 Å. In the crystal, mol-ecules are linked by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds, generating a three-dimensional network.
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